ATR-FTIR FOR DISCRIMINATION OF ESPRESSO AND AMERICANO COFFEE PODS
DOI:
https://doi.org/10.25186/cs.v13i4.1499Keywords:
Coffee brewing Single-serve brewer, Coffee pods, Extraction brew physiochemical properties, FTIR spectraAbstract
Roasted and ground coffee for encapsulation in single-serve capsules compatible with keurig® and coffee powder obtained from Nespresso® commercial capsules were analyzed for pH value, titratable acidity, moisture content, water activity and color (lightness); a data matrix that contains the physicochemical properties and the absorbance measurements using a baseline of 1600 to 1800 cm–1 by FTIR-ATR technique, was evaluated through the combined methods of principal component analysis (PCA) and cluster analysis in order to discriminate between the types of capsules. In the PCA biplot two distinct groups can be identified and in the cluster analysis two groups are that correspond to the two types of capsules. The results showed that FTIR-ATR based methods seem to be a promising alternative for the discrimination of coffee samples for the pods industry or for the type of consumption.References
ABDALLA, MA. Determination of caffeine, the active ingredient in different coffee drinks and its characterization by FTIR/ATR and TGA/DTA. International Journal of Engineering and Applied Sciences, Saudi Arabia , v. 2, n. 12, p. 85-89, dec. 2015.
BARBIN, DF. ; FELICIO, ALSM. ; SOL, D-W. ; NIXDORF, SL. ; HIROOKA, EY. Application of infrared spectral techniques on quality and compositional attributes of coffee: An overview. Food Research International, Londrina, v. 61, p. 23-32, jul. 2014.
BELCHIOR, V. ; BOTELHO, BG. ; OLIVEIRA, LS. ; FRANCA, AS. Attenuated total reflectance fourier transform spectroscopy (atr-ftir) and chemometrics for discrimination of espresso coffees with different sensory characteristics. Food Chemistry, Belo Horizonte, dec. 2017.
BOUHSAIN, Z. ; GARRIGUES, JM. ; GARRIGUES, S. ; DE LA GUARDIA, M. Flow injection fourier transform infrared determination of caffeine in coffee. Vibrational Spectroscopy, Valencia, v. 21, n. 1-2, p. 143-150, dec. 1999.
BRIANDET, R. ; KEMSLEY, EK. ; WILSON, RH. Approaches to adulteration detection in instant coffees using infrared spectroscopy and chemometrics. Journal of the Science of Food and Agriculture, Norwich, v. 71, n. 3, p. 359-366, jul. 1996.
BUFFO, RA. & CARDELLI-FREIRE, C. Coffee flavour: an overview. Flavour and Fragance Journal, Minnesota, v. 19, n. 2, p. 99–104, feb. 2004.
CRAIG, AP. ; BOTELHO, BG. ; OLIVEIRA, LS. ; FRANCA, AS. Mid infrared spectroscopy and chemometrics as tools for the classification of roasted coffees by cup quality. Food Chemistry, Belo Horizonte, v. 245, p. 1052-1061, apr. 2018.
CRAIG, AP. ; FRANCA, AS. ; OLIVEIRA, LS. Evaluation of the potential of ftir and chemometrics for separation between defective and non-defective coffees. Food Chemistry, Belo Horizonte, v. 132, p. 1368–1374, dec. 2012.
DAGHBOUCHE, Y. ; GARRIGUES S. ; VIDAL M. ; De la Guardia M. Flow injection Fourier transform infrared determination of caffeine in soft drinks. Analytical Chemistry, v. 69, n. 6, p. 1086-1091, 1997.
DESBROW, B.; HALL, S. ; IRWIN, C. caffeine content of nespresso® pod coffee® pod coffee. Journal of Nutrition & Intermediary Metabolism, Queensland, v. 8, p. 60-121, 2017.
ESTEBAN-DÍEZ, I. ; GONZÁLEZ- SAÍZ, JM. ; PIZARRO, C. Prediction of sensory properties of espresso from roasted coffee samples by near infrared spectroscopy. Analytica Chimica Acta, Logroño, v. 525, p. 171–182, nov. 2004.
FARAH, A. & DONANGELO, AM. Phenolic compounds in coffee. Brazilian Journal of Plant Physiology, Rio de Janeiro, v. 18, n. 1, p.23-36, mar. 2006.
FRANCA, AS. ; OLIVEIRA LS. ; OLIVEIRA, RCS. ; AGRESTI, PCM. ; AUGUSTI, R. A preliminary evaluation of the effect of processing temperature on coffee roasting degree assessment. Journal of Food Engineering, Belo Horizonte, v. 92, n. 3, p. 345–352, jun. 2009.
FUJIOKA, K. & SHIBAMOTO, T. Chlorogenic acid and caffeine contents in various commercial brewed coffees. Food Chemistry, Berkeley, v. 106, n. 1, p. 217–221, jan. 2008.
GALLIGNANI, M. ; TORRES, M. ; AYALA, C. ; BRUNETTO, MDR. Determination of caffeine in coffee by means fourier transform infrared spectrometry. Revista técnica de la facultad de ingeniería Universidad del Zulia, Zulia, v. 31, n. 2, p. 95-109, aug. 2008.
GARRIGUES, JM. ; BOUHSAIN, Z. ; GARRIGUES, S. ; DE LA GUARDIA, M. Fourier transform infrared determination of caffeine in roasted coffee samples. Analytical and Bioanalytical Chemistry, Valencia, v. 366, n. 3, p. 319–322, sep. 2000.
GLOESS, AN. ; SCHONBACHLER, B. ; KLOPPROGGE, B. ;D’AMBROSIO, L. ; CHATELAIN, K. ; BONGARTZ, A. ; STRITTMATTER, A. ; RAST, M. ; YERETZIAN, C. Comparision of nine common coffee extraction methods: instrumental and sensory analysis. European Food Research and Technology, Zurich , v. 236, n. 4, p. 607–627, jun. 2013.
KEMSLEY, EK. ; RUAULT, S. ; WILSON, RH. Discrimination between coffea arabica and coffea canephora variant robusta beans using infrared spectroscopy. Food Chemistry, Norwich, v. 54, n. 2, p. 321–326, jan. 1995.
LIANG, N. ; LU X. ; HU Y. ; KITTS D. Application of attenuated total reflectance-Fourier transformed infrared (ATR-FTIR) spectroscopy to determine chlorogenic acid isomer profile and antioxidant capacity of coffee beans. Journal of Agricultural and Food Chemistry, Vancouver, v. 64, n. 3, p. 681–689, jan. 2016a.
LIANG, N. ; XUE, W. ; KENNEPOHL, P. ; KITTS, DD. Interactions between major chlorogenic acid isomers and chemical changes in coffee brew that affect antioxidant activities. Food Chemistry, Vancouver, v. 213, p. 251–259, jun. 2016b.
NAJAFI, MN. ; HAMID, AS. ; AFSHIN, RK. Determination of caffeine in black tea leaves by fourier transform infrared spectrometry using multiple linear regression. Microchemical Journal, Tehran, v. 75, n. 3, p. 151–158, dec. 2003.
PARENTI, A. ; GUERRINI, L. ; MASELLA, P. ; SPINELLI, S. ; CALAMAI, L. ; SPUGNOLI, P. Comparison of espresso coffee brewing techniques. Journal of Food Engineering, Firenze, v. 121, p. 112-117, agu. 2013.
PIZARRO, C. ; ESTEBAN-DÍEZ, I. ; GONZÁLEZ-SÁIZ, JM. ; FORINA, M. Use of near-infrared spectroscopy and feature selection techniques for predicting the caffeine content and roasting color in roasted coffees. Journal of Agricultural and Food Chemistry, Logroño, v. 55, n. 18, p. 7477–7488, aug. 2007.
REIS, N. ; FRANCA, AS. ; OLIVEIRA, LS. Quantitative evaluation of multiple adulterants in roasted coffee by diffuse reflectance infrared fourier transform spectroscopy (DRIFTS) and chemometrics. Talanta, Belo Horizonte, v. 115, p. 563–568, jun. 2013b.
REIS, N. ; FRANCA, AS. ; OLIVEIRA, LS. Discrimination between roasted coffee, roasted corn and coffee husks by diffuse reflectance infrared fourier transform spectroscopy. Food Science and Technology, Belo Horizonte, v. 50, n. 2, p. 715-722, mar. 2013a.
RIVERA W. ; VELASCO, X. ; RINCÓN, CA. TGA and FTIR evaluation of composition changes produced by roasting of coffee beans. Revista Colombiana de Física, Popayán, v. 45, n. 3, p. 205-208, nov. 2013.
WANG, N. & LIM, LT. Fourier transform infrared and physicochemical analyses of roasted coffee. Journal of Agricultural and Food Chemistry, Guelph, v. 60, n. 21, p. 5446−5453, may. 2012.
WANG, X. ; WILLIAM, J. ; FU, Y. ; LIM, L.-T. Effects of capsule parameters on coffee extraction in single-serve brewer. Food Research International, Guelph, v. 89, p. 797–805, sep. 2016.
Published
How to Cite
Issue
Section
Os direitos autorais dos artigos publicados nesta revista pertencem aos autores, com os primeiros direitos de publicação pertencentes à revista. Como os artigos aparecem nesta revista com acesso aberto, eles podem ser usados livremente, com as devidas atribuições, em aplicativos educacionais e não comerciais.